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Vanadium


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Atomic symbol: V
Atomic number: 23
Atomic weight: 50.9415
Atomic volume: 8.78 cm3/mol
Density: 5.8 g/cm3
Period Number: 4
Group number: 5
Group name: Trans. Met.
Element classification: Metal


States


Phase at room temperature: Solid
Melting Point: 2163.2 K
Boiling point: 3623 K
Heat of fusion: 20.90 kJ/mol
Heat of vaporization: 0.452 kJ/mol


Energies


Ionization Energy: 6.746 eV
1st ionization energy: 650.3 kJ/mole
2nd ionization energy: 1413.5 kJ/mole
3rd ionization energy: 2828 kJ/mole
Electronegativity: 1.63
Electron affinity: 50.7 kJ/mole
Specific heat: 0.49 J/gK
Heat atomization: 514 kJ/mole atoms


Oxidation & Electrons


Shells: 2,8,11,2
Electron Shell Configuration: [Ar] 3d3 4s2
Minimum oxidation number: -1
Maximum oxidation number: 5
Minimum common oxidation number: 0
Maximum common oxidation no: 5


Appearance & Characteristics


Structure:: bcc: body-centered cubic
Color: bright white
Hardness: mohs
Toxicity: yes
Characteristics: soft
Uses: tool steel, V2O5 catalyst


Reactions


Reaction with air: mild, w/ht =>V2O5, VN
Reaction with 6M HCl: none
Reaction with 15M HNO3: mild
Reaction with 6M NaOH: none


Other Forms


Number of isotopes: 2
Oxide(s): VO V2O3 VO2 V2O5
Hydride(s): VH VH2
Chloride(s): VCl2 VCl3 VCl4


Radius


Atomic Radius: 134 pm
Ionic radius (1- ion): pm
Ionic radius (1+ ion): pm
Ionic radius (2- ion): pm
Ionic radius (2+ ion): 93 pm
Ionic radius (3+ ion): 78 pm


Conductivity


Thermal conductivity: 30.7 J/m-sec-deg
Electrical conductivity: 39.37 1/mohm-cm
Polarizability: 12.4 A^3


Abundance


Source: U, Pb vanadates (misc)
Relative abundance solar system: 2.467 log
Abundance earth's crust: 2.1 log
Estimated crustal abundance: 1.20×102 milligrams per kilogram
Estimated oceanic abundance: 2.5×10-3 milligrams per liter
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 


History


(Scandinavian goddess, Vanadis) Vanadium was first discovered by del Rio in 1801. Unfortunately, a French chemist incorrectly declared that del Rio's new element was only impure chromium. Del Rio thought himself to be mistaken and accepted the French chemists' statement.

The element was rediscovered in 1830 by Sefstrom, who named the element in honor of the Scandinavian goddess, Vanadis, because of its beautiful multicolored compounds. It was isolated in nearly pure form by Roscoe, who in 1867 reduced the chloride with hydrogen.

Vanadium of 99.3 to 99.8% purity was not produced until 1922.


Sources


Vanadium is found in about 65 different minerals among which are carnotite, roscoelite, vanadinite, and patronite, important sources of the metal. Vanadium is also found in phosphate rock and certain iron ores, and is present in some crude oils in the form of organic complexes. It is also found in small percentages in meteorites.

Commercial production from petroleum ash holds promise as an important source of the element. High-purity ductile vanadium can be obtained by reduction of vanadium trichloride with magnesium or with magnesium-sodium mixtures.

Much of the vanadium metal being produced is now made by calcium reduction of V2O5 in a pressure vessel, an adaption of a process developed by McKechnie and Seybair.


Properties


Pure vanadium is a bright white metal, and is soft and ductile. It has good corrosion resistance to alkalis, sulfuric and hydrochloric acid, and salt water, but the metal oxidizes readily above 6600C.

The metal has good structural strength and a low fission neutron cross section, making it useful in nuclear applications.


Uses


Vanadium is used in producing rust resistant and high speed tool steels. It is an important carbide stabilizer in making steels.

About 80% of the vanadium now produced is used as ferrovanadium or as a steel additive. Vanadium foil is used as a bonding agent in cladding titanium to steel. Vanadium pentoxide is used in ceramics and as a catalyst.

It is also used to produce a superconductive magnet with a field of 175,000 gauss.


Isotopes


Natural vanadium is a mixture of two isotopes, 50V (0.24%) and 51V (99.76%). 50V is slightly radioactive, having a half-life of > 3.9 x 1017 years. Nine other unstable isotopes are recognized.

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