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Nitrogen


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Atomic symbol: N
Atomic number: 7
Atomic weight: 14.0067
Atomic volume: 17.3 cm3/mol
Density: 0.0012506 g/cm3
Period Number: 2
Group number: 15
Group name: Non-Metal
Element classification: Non-metal


States


Phase at room temperature: Gas
Melting Point: 63.34 K
Boiling point: 77.4 K
Heat of fusion: 0.3604 kJ/mol
Heat of vaporization: 2.7928 kJ/mol


Energies


Ionization Energy: 14.534 eV
1st ionization energy: 1402.3 kJ/mole
2nd ionization energy: 2856 kJ/mole
3rd ionization energy: 4578 kJ/mole
Electronegativity: 3.04
Electron affinity: -6.75 kJ/mole
Specific heat: 1.04 J/gK
Heat atomization: 473 kJ/mole atoms


Oxidation & Electrons


Shells: 2,5
Electron Shell Configuration: [He] 2s2 2p3
Minimum oxidation number: -3
Maximum oxidation number: 5
Minimum common oxidation number: -3
Maximum common oxidation no: 5


Appearance & Characteristics


Structure:: ?
Color: colorless
Hardness: mohs
Toxicity: no
Characteristics: diatomic(N2)
Uses: fertilizer, cryogenics


Reactions


Reaction with air: none
Reaction with 6M HCl: none
Reaction with 15M HNO3: none
Reaction with 6M NaOH: none


Other Forms


Number of isotopes: 2
Oxide(s): N2O NO NO2 N2O2
Hydride(s): NH2 N2H2 HN2
Chloride(s): NCl2


Radius


Atomic Radius: 70 pm
Ionic radius (1- ion): pm
Ionic radius (1+ ion): pm
Ionic radius (2- ion): pm
Ionic radius (2+ ion): pm
Ionic radius (3+ ion): 30 pm


Conductivity


Thermal conductivity: 0.03 J/m-sec-deg
Electrical conductivity: 0 1/mohm-cm
Polarizability: 1.1 A^3


Abundance


Source: Air
Relative abundance solar system: 6.496 log
Abundance earth's crust: 1.3 log
Estimated crustal abundance: 1.9×101 milligrams per kilogram
Estimated oceanic abundance: 5×10-1 milligrams per liter
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 


History


(L. nitrum, Gr. Nitron, native soda; and genes, forming) Nitrogen was discovered by chemist and physician Daniel Rutherford in 1772. He removed oxygen and carbon dioxide from air and showed that the residual gas would not support combustion or living organisms. At the same time there were other noted scientists working on the problem of nitrogen. These included Scheele, Cavendish, Priestley, and others. They called it ?burnt" or" dephlogisticated air,” which meant air without oxygen.


Sources


Nitrogen gas (N2) makes up 78.1% of the Earth’s air, by volume. The atmosphere of Mars, by comparison, is only 2.6% nitrogen. From an exhaustible source in our atmosphere, nitrogen gas can be obtained by liquefaction and fractional distillation. Nitrogen is found in all living systems as part of the makeup of biological compounds.


Compounds


Sodium nitrate (NaNO3) and potassium nitrate (KNO3) are formed by the decomposition of organic matter with compounds of these metals present. In certain dry areas of the world these saltpeters are found in quantity and are used as fertilizers. Other inorganic nitrogen compounds are nitric acid (HNO3), ammonia (NH3), the oxides (NO, NO2, N2O4, N2O), cyanides (CN-), etc.

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