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Erbium


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Atomic symbol: Er
Atomic number: 68
Atomic weight: 167.26
Atomic volume: 18.4 cm3/mol
Density: 9.05 g/cm3
Period Number: 6
Group number: none
Group name: Rare Earth, Lanthanides
Element classification: Metal


States


Phase at room temperature: Solid
Melting Point: 1795.2 K
Boiling point: 3173 K
Heat of fusion: 19.90 kJ/mol
Heat of vaporization: 261.0 kJ/mol


Energies


Ionization Energy: 6.108 eV
1st ionization energy: 588.7 kJ/mole
2nd ionization energy: 1151 kJ/mole
3rd ionization energy: 2194 kJ/mole
Electronegativity: 1.24
Electron affinity: 50 kJ/mole
Specific heat: 0.17 J/gK
Heat atomization: 317 kJ/mole atoms


Oxidation & Electrons


Shells: 2,8,18,30,8,2
Electron Shell Configuration: [Xe] 4f12 6s2
Minimum oxidation number: 0
Maximum oxidation number: 3
Minimum common oxidation number: 0
Maximum common oxidation no: 3


Appearance & Characteristics


Structure:: hcp: hexagonal close pkd
Color: silvery-white
Hardness: mohs
Toxicity: ?
Characteristics: ?
Uses: alloys, photogr. filter


Reactions


Reaction with air: vigorous, =>Er2O3
Reaction with 6M HCl: mild, =>H2, ErCl3
Reaction with 15M HNO3: mild, =>Er(NO3)3
Reaction with 6M NaOH: ?


Other Forms


Number of isotopes: 6
Oxide(s): Er2O3
Hydride(s): ErH2 ErH3
Chloride(s): ErCl3


Radius


Atomic Radius: 176 pm
Ionic radius (1- ion): pm
Ionic radius (1+ ion): pm
Ionic radius (2- ion): pm
Ionic radius (2+ ion): pm
Ionic radius (3+ ion): 103 pm


Conductivity


Thermal conductivity: 14.5 J/m-sec-deg
Electrical conductivity: 14.1 1/mohm-cm
Polarizability: 22.7 A^3


Abundance


Source: Monazite(phosphate),bastnaesite
Relative abundance solar system: -0.601 log
Abundance earth's crust: 0.4 log
Estimated crustal abundance: 3.5 milligrams per kilogram
Estimated oceanic abundance: 8.7×10-7 milligrams per liter
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 


History


(Ytterby, a town in Sweden) Erbium, one of the so-called rare-earth elements on the lanthanide series, is found in the minerals mentioned under dysprosium. In 1842 Mosander separated "yttria" found in the mineral gadolinite, into three fractions which he called yttria, erbia, and terbia. The names erbia and terbia became confused in this early period. After 1860, Mosander's terbia was known as erbia, and after 1877, the earlier known erbia became terbia. The erbia of this period was later shown to consist of five oxides, now known as erbia, scandia, holmia, thulia and ytterbia. By 1905 Urbain and James independently succeeded in isolating fairly pure Er2O3. Klemm and Bommer first produced reasonably pure erbium metal in 1934 by reducing the anhydrous chloride with potassium vapor.


Properties


The pure metal is soft and malleable and has a bright, silvery, metallic luster. As with other rare-earth metals, its properties depend to a certain extent on the impurities present. The metal is fairly stable in air and does not oxidize as rapidly as some of the other rare-earth metals. Naturally occurring erbium is a mixture of six isotopes, all of which are stable. Nine radioactive isotopes of erbium are also recognized. Recent production techniques, using ion-exchange reactions, have resulted in much lower prices of the rare-earth metals and their compounds in recent years. Most of the rare-earth oxides have sharp absorption bands in the visible, ultraviolet, and near infrared. This property, associated with the electronic structure, gives beautiful pastel colors to many of the rare-earth salts.


Uses


Erbium is finding nuclear and metallurgical uses. Added to vanadium, for example, erbium lowers the hardness and improves workability. Erbium oxide gives a pink color and has been used as a colorant in glasses and porcelain enamel glazes.

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