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Copper


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Atomic symbol: Cu
Atomic number: 29
Atomic weight: 63.546
Atomic volume: 7.1 cm3/mol
Density: 8.96 g/cm3
Period Number: 4
Group number: 11
Group name: Trans. Met.
Element classification: Metal


States


Phase at room temperature: Solid
Melting Point: 1356.6 K
Boiling point: 2843 K
Heat of fusion: 13.050 kJ/mol
Heat of vaporization: 300.30 kJ/mol


Energies


Ionization Energy: 7.726 eV
1st ionization energy: 745.4 kJ/mole
2nd ionization energy: 1957.9 kJ/mole
3rd ionization energy: 3553.5 kJ/mole
Electronegativity: 1.95
Electron affinity: 118.5 kJ/mole
Specific heat: 0.38 J/gK
Heat atomization: 338 kJ/mole atoms


Oxidation & Electrons


Shells: 2,8,18,1
Electron Shell Configuration: [Ar] 3d10 4s1
Minimum oxidation number: 0
Maximum oxidation number: 4
Minimum common oxidation number: 0
Maximum common oxidation no: 2


Appearance & Characteristics


Structure:: fcc: face-centered cubic
Color: orange-red
Hardness: 2.75 mohs
Toxicity: ?
Characteristics: soft, ductile
Uses: wire, bronze, coins


Reactions


Reaction with air: mild, w/ht =>CuO, Cu2O
Reaction with 6M HCl: none
Reaction with 15M HNO3: mild, =>Cu(NO3)2, NOx
Reaction with 6M NaOH: ?


Other Forms


Number of isotopes: 2
Oxide(s): Cu2O CuO
Hydride(s): CuH
Chloride(s): CuCl CuCl2


Radius


Atomic Radius: 128 pm
Ionic radius (1- ion): pm
Ionic radius (1+ ion): 91 pm
Ionic radius (2- ion): pm
Ionic radius (2+ ion): 87 pm
Ionic radius (3+ ion): 68 pm


Conductivity


Thermal conductivity: 401 J/m-sec-deg
Electrical conductivity: 595.8 1/mohm-cm
Polarizability: 6.7 A^3


Abundance


Source: Cu pyrite,chalcocite(sulfide)
Relative abundance solar system: 2.718 log
Abundance earth's crust: 1.7 log
Estimated crustal abundance: 6.0×101 milligrams per kilogram
Estimated oceanic abundance: 2.5×10-4 milligrams per liter
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 


History


(Latin cuprum , from the island of Cyprus) It is believed that copper has been mined for 5,000 years.


Sources


Copper occasionally occurs natively, and is found in many minerals such as cuprite, malachite, azurite, chalcopyrite, and bornite.

Large copper ore deposits are found in the U.S., Chile, Zambia, Zaire, Peru, and Canada. The most important copper ores are the sulfides, the oxides, and carbonates. From these, copper is obtained by smelting, leaching, and by electrolysis.


Properties


Copper is reddish and takes on a bright metallic luster. It is malleable, ductile, and a good conductor of heat and electricity (second only to silver in electrical conductivity).


Uses


The electrical industry is one of the greatest users of copper. Iron's alloys -- brass and bronze -- are very important: all American coins are copper alloys and gun metals also contain copper.

Copper has wide use as an agricultural poison and as an algaecide in water purification. Copper compounds, such as Fehling's solution, are widely used in analytical chemistry tests for sugar.

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