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Californium


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Atomic symbol: Cf
Atomic number: 98
Atomic weight: (251)
Atomic volume: ?
Density: ?
Period Number: 7
Group number: none
Group name: Rare Earth, Actinides
Element classification: Metal


States


Phase at room temperature: Solid
Melting Point: 1173.2 K
Boiling point: K
Heat of fusion: ?
Heat of vaporization: ?


Energies


Ionization Energy: 6.30 eV
1st ionization energy: 608 kJ/mole
2nd ionization energy: kJ/mole
3rd ionization energy: kJ/mole
Electronegativity: 1.3
Electron affinity: kJ/mole
Specific heat: ?
Heat atomization: kJ/mole atoms


Oxidation & Electrons


Shells: 2,8,18,32,28,8,2
Electron Shell Configuration: [Rn] 5f10 7s2
Minimum oxidation number: 0
Maximum oxidation number: 4
Minimum common oxidation number: 0
Maximum common oxidation no: 3


Appearance & Characteristics


Structure:: ?
Color: ?
Hardness: mohs
Toxicity: ?
Characteristics: Radioactive
Uses: neutron source


Reactions


Reaction with air: ?
Reaction with 6M HCl: ?
Reaction with 15M HNO3: ?
Reaction with 6M NaOH: ?


Other Forms


Number of isotopes: 0
Oxide(s): CfO Cf2O3 CfO2
Hydride(s): ?
Chloride(s): CfCl3


Radius


Atomic Radius: 186 pm
Ionic radius (1- ion): pm
Ionic radius (1+ ion): pm
Ionic radius (2- ion): pm
Ionic radius (2+ ion): pm
Ionic radius (3+ ion): 109 pm


Conductivity


Thermal conductivity: J/m-sec-deg
Electrical conductivity: 1/mohm-cm
Polarizability: 20.5 A^3


Abundance


Source: Synthetic
Relative abundance solar system: log
Abundance earth's crust: log
Estimated crustal abundance: Not Applicable
Estimated oceanic abundance: Not Applicable
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 


History


(State and University of California) Californium, the sixth transuranium element to be discovered, was produced by Thompson, Street, Ghioirso, and Seaborg in 1950 by bombarding microgram quantities of 242Cm with 35 MeV helium ions in the Berkeley 60-inch cyclotron. Californium (III) is the only ion stable in aqueous solutions, all attempts to reduce or oxidize californium (III) having failed. The isotope 249Cf results from the beta decay of 249Bk while the heavier isotopes are produced by intense neutron irradiation by the reactions. The existence of the isotopes 249Cf, 250Cf, 251Cf, and 252Cf makes it feasible to isolate californium in weighable amounts so that its properties can be investigated with macroscopic quantities.


Properties


Californium-252 is a very strong neutron emitter. One microgram releases 170 million neutrons per minute, which presents biological hazards. Proper safeguards should be used in handling californium. Reduction of californium to its metallic state has not yet been accomplished. Because californium is a very efficient source of neutrons, many new uses are expected for it. It has already found use in neutron moisture gauges and in well-logging (the determination of water and oil-bearing layers). It is also being used as a portable neutron source for discovery of metals such as gold or silver by on-the-spot activation analysis. 252Cf is now being offered for sale by the O.R.N.L. at a cost of $10/mg. As of May, 1975, more than 63 mg have been produced and sold. It has been suggested that californium may be produced in certain stellar explosions, called supernovae, for the radioactive decay of 254Cf (55-day half-life) agrees with the characteristics of the light curves of such explosions observed through telescopes. This suggestion, however, is questioned.

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